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MATERIAL SAFETY DATA SHEETS
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MSDS No: 106-98-9
Date: 07/23/2008 |
| SUPPLIER ADDRESS: | 6141 Easton Road, Bldg. 1
PO Box 310
Plumsteadville, PA 18949-0310 | EMERGENCY PHONE NUMBER: | (215) 766-8861 |
| PRODUCT NAME: | 1-BUTENE | SYNONYMS: | None |
| 2. COMPOSITION, INFORMATION ON INGREDIENTS |
| Ingredient Name | Formula | | CAS # | | Concentration | | ACGIH TLV | | OSHA PEL | | MAC | | Other STEL |
|---|
 1-BUTENE | C4H8 | | 106-98-9 | | 99+% | | 250 | | S/A | | S/A | | S/A |
| Note: | NE = NONE ESTABLISHED | S/A = SIMPLE ASPHYXIANT |
| 3. HAZARD INDENTIFICATION |
* * * EMERGENCY OVERVIEW * * *
Flammable liquid and gas under pressure
Can form explosive mixtures with air.
May cause frostbite.
POTENTIAL HEALTH EFFECTS
ROUTES OF ENTRY: Inhalation
ACUTE EFFECTS: Material acts as a simple asphyxiant by displacing air necessary for life.Symptoms include rapid respiration, muscular incoordination, fatigue, dizziness, nausea, vomiting, unconsciousness, and death.Pressure drop through valves and piping may cause extreme cold and frostbite on contact.
CHRONIC EFFECTS: None known
MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: None known
OTHER EFFECTS OF OVEREXPORSURE: None
CARCINOGENICITY (US ONLY):
NTP - No
IARC MONOGRAPHS - No
OSHA REGULATED - No
INHALATION: Immediately remove victim to fresh air.If breathing has stopped, give artificial respiration.If breathing is difficult, give oxygen.
EYE CONTACT: Immediately flush with copious amounts of water for at least 15 minutes.
SKIN CONTACT: If frostbite occurs, flush affected areas with lukewarm water.
INGESTION: None
IN EVENT OF EXPOSURE, CONSULT A PHYSICIAN
NOTE TO PHYSICIAN: None
| 5. FIRE FIGHTING MEASURES |
FLASH POINT: -80 deg.C
AUTOIGNITION TEMPERATURE: 385 deg.C
FLAMMABLE LIMITS: Vol.%
EXTINGUISHING MEDIA: Carbon dioxide, foam, or dry chemical.
SPECIAL FIRE FIGHTING INSTRUCTION AND EQUIPMENT: Wear self-contained breathing apparatus and full protective clothing.Keep fire exposed cylinders cool with water spray.If possible, stop the product flow.
HAZARDOUS COMBUSTION PRODUCTS: Toxic carbon monoxide may be given off during combustion.
UNUSUAL FIRE AND EXPLOSION HAZARDS: Cylinder rupture may occur under fire conditions.May form explosive mixture in air.Vapors may travel a considerable distance to the source of ignition and flash back.
| 6. ACCIDENTAL RELEASE MEASURES |
CLEAN UP PROCEDURES: Evacuate and ventilate area.Shut off source if possible and remove source of heat.Remove leaking cylinder to exhaust hood or safe outdoor area.
SPECIALIZED EQUIPMENT: None
PRECAUTIONS TO BE TAKEN IN HANDLING: Secure cylinder when using to protect from falling.Use suitable hand truck to move cylinders.
PRECAUTIONS TO BE TAKEN IN STORAGE: Store in well ventilated areas.Store away from heat, flame, and sparks.Keep valve protection cap on cylinders when not in use.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION |
ENGINEERING CONTROLS: Provide adequate general and local exhaust ventilation to maintain concentrations below flammable limits and to avoid asphyxiation.
EYE / FACE PROTECTION: Safety glasses
SKIN PROTECTION: Protective gloves to prevent contact with cold equipment.
RESPIRATORY PROTECTION: In case of leakage, use self-contained breathing apparatus.
OTHER PROTECTIVE EQUIPMENT: Safety shoes when handling cylinders.
| 9. PHYSICAL AND CHEMICAL PROPERTIES |
APPEARANCE: Colorless
ODOR: Hydrocarbon odor.
PHYSICAL PRESSURE: Gas
VAPOR PRESSURE: @21 deg.C: 3480 mm Hg
VAPOR DENSITY (AIR=1): 1.9
BOILING POINT (C): -6.47
SOLUBILITY IN WATER: Insoluble
SPECIFIC GRAVITY (H2O=1): Gas
EVAPORATION RATE: Gas
ODOR THRESHOLD: 0.93 to 1.3 ppm
| 10. STABILITY AND REACTIVITY |
STABILITY: Stable under normal storage conditions.
CONDITIONS TO AVOID: Storage in poorly ventilated areas.Storage near a heat source.
MATERIALS TO AVOID: Oxidizing agents.
HAZARDOUS POLYMERIZATION: Will not occur.
HAZARDOUS DECOMPOSITION: Toxic carbon monoxide.
| 11. TOXICOLOGICAL INFORMATION |
LETHAL CONCENTRATION (LC50): NONE ESTABLISHED
LETHAL DOSE 50 (LD50): N/Ap
TERATOGENICITY: N/Ap
REPRODUCTIVE EFFECTS: N/Ap
MUTAGENICITY: N/Ap
| 12. ECOLOGICAL INFORMATION |
No adverse ecological effects are expected.
| 13. DISPOSAL CONSIDERATIONS |
WASTE DISPOSAL METHOD: Dispose of non-refillable cylinders in accordance with federal, state and local regulations. Allow gas to vent slowly to atmosphere in an unconfined area or exhaust hood. If the cylinders are the refillable type, return cylinders to supplier with any valve outlet plugs or caps secured and valve protection caps in place.
| 14. TRANSPORT INFORMATION |
CONCENTRATION: 99+%
DOT DESCRIPTION (US ONLY):
PROPER SHIPPING NAME: 1-Butene
HAZARD CLASS: 2.1 (flammable)
INDENTIFICATION NUMBER: UN1012
REPORTABLE QUANTITIES: None
LABELING: FLAMMABLE GAS
ADR / RID (EU Only): Class 2, 1F
SPECIAL PRECAUTIONS: Cylinders should be transported in a secure upright position in a well ventilated truck.
| 15. REGULATORY INFORMATION |
OSHA: Process Safety Management: Material is not listed in appendix A of 29 CFR 1910.119 as highly hazardous chemical.
TSCA: Material is listed in TSCA inventory.
SARA: The threshold planning quantity for material is 10,000 lbs.
EU NUMBER: 203-449-2
NUMBER IN ANNEX 1 OF DIR 67/548: Material is listed in annex 1.
EU CLASSIFICATION: N/Av
R: 13
S: 9-16-33
OTHER PRECAUTIONS: Protect containers from physical damage. Do not deface cylinders or labels. Cylinders should be refilled by qualified producers of compressed gas. Shipment of a compressed gas cylinder which has not been filled by the owner or with his written consent is a violation of federal law (49 CFR).
ABBREVIATIONS: N/Ap - Not Applicable N/Av - Not Available SA - Simple Asphyxiant NE - None Established
DISCLAIMER: Information included in this document is given to the best of our knowledge, however, no warranty is made that the information is accurate or complete. We do not accept any responsibility for damages by the use of the document.
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